Hawke's Bay and parts of the Upper South Island have neared 35C as temperatures continue to climb this afternoon.
Meanwhile in the wider Nelson area, Richmond's minimum temperature of 24.3C has set a new record.
It wasn't the only record-breaking temperature for the region however, Richmond reached a scorching 33.8C this afternoon - the warmest January temperature on record.
Records began in the area 157 years ago.
The temperature neared 35C in Blenheim yesterday. The town is expected to top that today, with Gisborne close behind on 34C.
MetService said the hottest temperatures over the week would likely be felt in the eastern parts of the country, with Tīmaru and Blenheim to Napier, and Hastings expected to simmer in heat up to six degrees higher than average.
Kerikeri, Paihia, Tauranga, Napier, Hastings, Masterton, Nelson, Christchurch, Ashburton, Wanaka and Alexandra were all expected to top 30C, with other centres largely in the high 20s.
New Zealanders have been urged to take precautions including drinking extra water, avoiding liquor and keeping cool in the shade.
Fire and Emergency said the fire danger was particularly bad in Northland, Nelson, Marlborough and Canterbury where there are total fire bans in place.
The heatwave in Australia has caused Adelaide to reach 46.6C, beating temperature records for all Australian cities, and has led to fires, power blackouts and wildlife deaths including wild horses, bats and fish.